Escudo de la República de Colombia
Sistema Nacional de Biliotecas - Repositorio Institucional Universidad Nacional de Colombia Biblioteca Digital - Repositorio Institucional UN Sistema Nacional de Bibliotecas UN

Synthesis and modification of beta zeolite for use in toluene disproportionation reaction

Mesa Espinal, Santiago and Arboleda, Johana and Echavarría, Adriana (2016) Synthesis and modification of beta zeolite for use in toluene disproportionation reaction. DYNA, 83 (196). pp. 184-193. ISSN 2346-2183

Texto completo

[img]
Vista previa
PDF - Versión Publicada
Available under License Creative Commons Attribution Non-commercial No Derivatives.

1MB

URL oficial: https://revistas.unal.edu.co/index.php/dyna/articl...

Resumen

In this paper zeolite Beta was synthesized and characterized by XRD, ATG, ATD, XRF and SEM. Subsequently various modifications were made using a surface passivation process in liquid phase with tetraethylorthosilicate (TEOS), using two loads of TEOS and three passivation cycles, in order to obtain six catalysts. These materials were characterized by NH3-TPD and tested in tolune disproportionation reaction, under different conditions of pressure and temperature. As modification cycles were increased for each catalyst, there was a change in the acidity of the solids, mainly due to deposition of an inert layer of silica on the external surface. These results were confirmed with the improvement in para-selectivity and decreasing in conversion. Despite zeolite Beta is a large pore zeolite, an improvement of the para-selectivity was obtained, achieving almost stable values for the entire range of temperature and pressure conditions.

Tipo de documento:Artículo - Article
Palabras clave:Beta zeolita, Surface Passivation, Catalysis, Toluene Disproportionation, Para-selectivity
Temática:6 Tecnología (ciencias aplicadas) / Technology > 62 Ingeniería y operaciones afines / Engineering
Unidad administrativa:Revistas electrónicas UN > Dyna
Código ID:58894
Enviado por : Dirección Nacional de Bibliotecas STECNICO
Enviado el día :31 Oct 2017 17:20
Ultima modificación:27 Noviembre 2017 22:04
Ultima modificación:27 Noviembre 2017 22:04
Exportar:Clic aquí
Estadísticas:Clic aquí
Compartir:

Solamente administradores del repositorio: página de control del ítem

Vicerrectoría de Investigación: Número uno en investigación
Indexado por:
Indexado por Scholar Google WorldCat DRIVER Registry of Open Access Repositories OpenDOAR Metabiblioteca BDCOL OAIster Red de repositorios latinoamericanos DSpace BASE Open archives La referencia Colombiae Open Access Theses and Dissertations Tesis latinoamericanas CLACSO
Este sitio web se ve mejor en Firefox